Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes
| Autor: | Bassam K. Alnasleh, William M. Sherrill, Michael Rubin |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
chemistry.chemical_classification
Cyclopropanes Double bond Phosphines Organic Chemistry chemistry.chemical_element Stereoisomerism Cyclopropene Biochemistry Catalysis chemistry.chemical_compound Organophosphorus Compounds chemistry Computational chemistry Organic chemistry Physical and Theoretical Chemistry Phosphorylation Palladium |
| Zdroj: | Organic letters. 10(15) |
| ISSN: | 1523-7060 |
| Popis: | Novel transition-metal-catalyzed addition of P−H entities across the cyclopropene double bond has been developed. This transformation allows for mild and efficient preparation of phosphorus-containing cyclopropanes in good yields and high degrees of diastereoselectivity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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