A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties
| Autor: | Muammer Kavanoz, Małgorzata Hołyńska, Hamide Merve Çepni, Selçuk Demir |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_element
General Chemistry Crystal structure Pyrazole 010402 general chemistry Electrochemistry 01 natural sciences Copper Combinatorial chemistry 0104 chemical sciences Characterization (materials science) chemistry.chemical_compound chemistry 0103 physical sciences 010306 general physics Thermal analysis |
| Zdroj: | Zeitschrift für Naturforschung B. 71:305-310 |
| ISSN: | 1865-7117 0932-0776 |
| DOI: | 10.1515/znb-2015-0197 |
| Popis: | A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands (pdc3−), [Me2NH2]4[Cu4(pdc)4], was synthesized using solvothermal and metal oxidation routes and characterized by elemental analysis, infrared, thermogravimetry/differential thermal analysis, and room-temperature magnetic measurements. The structure of the complex was determined by single-crystal X-ray diffraction. It comprises dimethylammonium cations and complex anions containing four Cu2+ cations. The crystal structure is stabilized by N–H···O hydrogen bonds. In addition, the electrochemical behavior was studied. |
| Databáze: | OpenAIRE |
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