Stabilization of a two-coordinate, acyclic diaminosilylene (ADASi): completion of the series of isolable diaminotetrylenes, :E(NR2)2(E = group 14 element)
| Autor: | Terrance J. Hadlington, Cameron Jones, Simon Aldridge, Joseph A. B. Abdalla, Rémi Tirfoin |
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| Rok vydání: | 2016 |
| Předmět: |
Series (mathematics)
010405 organic chemistry Chemistry Ligand Stereochemistry Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Specific orbital energy Group (periodic table) Materials Chemistry Ceramics and Composites Reactivity (chemistry) |
| Zdroj: | Chemical Communications. 52:1717-1720 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c5cc09673a |
| Popis: | An extremely bulky boryl-amide ligand, [N(SiMe3){B(DAB)}](-) (TBoN; DAB = (DipNCH)2, Dip = C6H3Pr(i)2-2,6), has been utilised in the preparation of the first isolable, two-coordinate acyclic diaminosilylene (ADASi), viz. :Si(TBoN)2. This is shown to have a frontier orbital energy separation, and presumed level of reactivity, intermediate between those of the two classes of previously reported isolable two-coordinate, acyclic silylenes. |
| Databáze: | OpenAIRE |
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