Experimental observation of hysteresis in a coherent metal-hydride phase transition

Autor: Ola Hartmann, Sotirios A. Droulias, Gunnar K. Pálsson, Björgvin Hjörvarsson, Max Wolff, Martin Brischetto, Wen Huang
Rok vydání: 2017
Předmět:
Zdroj: Journal of Physics: Condensed Matter. 29:495701
ISSN: 1361-648X
0953-8984
DOI: 10.1088/1361-648x/aa9696
Popis: We investigate the hysteresis obtained in the hydrogen absorption and desorption cycle for a single crystal [Formula: see text] superlattice. Below the critical temperature, a small but clear hysteresis is observed in the pressure-composition isotherms, while it is absent above. The experimental results thereby prove the relevance of macroscopic energy barriers for obtaining hysteresis in coherent structural transformations. The textured Pd layer exhibits substantially larger hysteresis effects, which can be related to an irreversible energy loss caused by defect generation in Pd.
Databáze: OpenAIRE