Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes
| Autor: | Bernabé F. Perandones, Javier Ruiz |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: |
Magnetic Resonance Spectroscopy
Stereochemistry chemistry.chemical_element Manganese Medicinal chemistry Catalysis Metal chemistry.chemical_compound Isomerism Materials Chemistry Molecule Thiazole Oxazoles Oxazole Metals and Alloys General Chemistry Tautomer Surfaces Coatings and Films Electronic Optical and Magnetic Materials Thiazoles chemistry Metals visual_art Ceramics and Composites visual_art.visual_art_medium Methane Organogold Compounds Carbene |
| Zdroj: | SCOPUS RUO. Repositorio Institucional de la Universidad de Oviedo instname |
| Popis: | Oxazole and thiazole molecules N-coordinated to manganese(i) are transformed into their corresponding 2,3-dihydrooxazol-2-ylidene and 2,3-dihydrothiazol-2-ylidene carbene tautomers by acid-base reactions, and subsequently transmetalated to gold(i), via isolable heterometallic intermediates. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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