Spatial distribution and speciation of Rare Earth Elements in mine tailings from ion-adsorption deposits in Southern China
| Autor: | Sharon E. Bone, Noémie Janot, Françoise Watteau, Camille Rivard, Ye-Tao Tang, Hermine Huot, Emmanuelle Montargès-Pelletier |
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| Přispěvatelé: | Interactions Sol Plante Atmosphère (UMR ISPA), Ecole Nationale Supérieure des Sciences Agronomiques de Bordeaux-Aquitaine (Bordeaux Sciences Agro)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Laboratoire Interdisciplinaire des Environnements Continentaux (LIEC), Institut Ecologie et Environnement (INEE), Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Terre et Environnement de Lorraine (OTELo), Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), Laboratoire Sols et Environnement (LSE), Université de Lorraine (UL)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Sun Yat-Sen University [Guangzhou] (SYSU), Synchrotron SOLEIL (SSOLEIL), Centre National de la Recherche Scientifique (CNRS), Stanford Synchrotron Radiation Lightsource (SSRL SLAC), SLAC National Accelerator Laboratory (SLAC), Stanford University-Stanford University, Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Terre et Environnement de Lorraine (OTELo), Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)-Institut Ecologie et Environnement (INEE), Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Janot, Noémie |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Goldschmidt 2021 Goldschmidt 2021, Jul 2021, Virtual, France |
| Popis: | International audience; Rare Earth Elements (REEs) are essential components of many high-tech products. In industrial materials, REEs come at 90% from Southern China ion-adsorption deposits, from which they are recovered by heap leaching using ammonium sulfate. Such large-scale process leads to severe environmental damage, and produces large tailings. Elucidating the nature of REE-bearing phases in these mine tailings is critical for predicting REE dynamics and designing a successful sustainable reclamation strategy, phyto-stabilization being currently tested.First investigations on the tailings soils revealed their high heterogeneous mineral composition, supporting the need for micro-scale investigation. XRD and TEM-EDXS identified quartz, K-feldspars and kaolinite as major phases, and optical microscope observations evidenced Fe-rich weathered layers surrounding particles, as well as organic material that might play a role in REEs distribution.X-ray spectromicroscopy analyses of soil thin sections (bare and planted) were performed at SSRL (beamline 2-3) and SOLEIL (LUCIA). We targeted the most concentrated REEs in the bulk soil, i.e., La, Ce and Nd. Overlaps in the fluorescence lines of REEs and transition metals (Ba, Ti) obliged us to perform fitting of the fluorescence signal in each pixel of the maps. Then, µXANES spectra at REE L-edges were collected to confirm the presence of REEs. The use of µXANES allowed us to detect very low quantities of REEs that were not detectable in global fluorescence maps. The combination of spectromicroscopy and fluorescence mapping was crucial and powerful to detect low levels of REEs in heterogeneous material.We evidenced the co-localization of REEs with Fe oxides, and, in reclaimed and vegetated samples, with roots. The high number of measurements performed on LUCIA beamline showed us that Ce speciation was predominantly Ce4+ when not accompanied by others REEs. In contrast, Ce3+ is systematically associated with Nd3+ and La3+.This work is, to our knowledge, the first to address REE distribution and speciation in soils. It provides significantly enhanced understanding of processes governing REE behaviour in mine tailings and will help designing successful reclamation techniques of contaminated land. It will contribute to validate process-based geochemical models describing REE behaviour, allowing to predict REE fate with ongoing reclamation. |
| Databáze: | OpenAIRE |
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