A new bis-tetraamine ligand with a chromophoric 4-(9-anthracenyl)-2,6-dimethylpyridinyl linker for glyphosate and ATP sensing
| Autor: | Loïc J. Charbonnière, Raphaël Tripier, Sabah Abada, Nathalie Le Bris, Mourad Elhabiri, Jacky Pouessel |
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| Přispěvatelé: | Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA), Université de Brest (UBO)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Brestois Santé Agro Matière (IBSAM), Université de Brest (UBO), Institut Pluridisciplinaire Hubert Curien (IPHC), Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de chimie moléculaire (LCM), Université de Strasbourg (UNISTRA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2013 |
| Předmět: |
Anions
Fluorophore Magnetic Resonance Spectroscopy Stereochemistry Pyridines Glycine Protonation 010402 general chemistry Ligands 01 natural sciences Inorganic Chemistry chemistry.chemical_compound Adenosine Triphosphate Polyamines [CHIM.COOR]Chemical Sciences/Coordination chemistry Nucleotide chemistry.chemical_classification Anthracenes [CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry Ligand Herbicides Nuclear magnetic resonance spectroscopy Hydrogen-Ion Concentration Combinatorial chemistry Fluorescence 0104 chemical sciences chemistry Potentiometry Spectrophotometry Ultraviolet Linker Adenosine triphosphate |
| Zdroj: | Dalton Transactions Dalton Transactions, Royal Society of Chemistry, 2013, 42 (14), ⟨10.1039/c3dt32325k⟩ |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c3dt32325k⟩ |
| Popis: | International audience; The synthesis of a new linear bis-tetraamine ligand L1, based on two 1,4,8,11-tetraazaundecane units grafted at the 2 and 6 positions of a pyridinyl linker substituted by an anthracenyl fluorophore in the para position, is described and anion complexation studies of L1 with anionic substrates are reported. The protonation pattern and the study of the binding properties of L1 in an aqueous medium with two anionic substrates, the nucleotide adenosine triphosphate (ATP) and the herbicide glyphosate (N-(phosphonomethyl)glycine, PMG), were investigated by means of potentiometry, NMR spectroscopy and absorption and emission spectroscopic techniques. To decipher the impact of the chromophoric linker on the complexation process and to highlight its optical properties, a comparison is established with its previously reported analog L2 devoid of the anthracenyl group. The results unambiguously show that the protonation and complexation properties are preserved despite the presence of the bulky linker, allowing for the use of L1 as a fluorescent sensor for ATP and PMG. |
| Databáze: | OpenAIRE |
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