Hybrid lanthanide double-deckers based on calixarene and polyoxometalate units

Autor:	Yushu Jiao, Sergio Sanz, Natalya V. Izarova, Jan van Leusen, Sidra Sarwar, Scott J. Dalgarno, Euan K. Brechin, Paul Kögerler
Rok vydání:	2022
Předmět:	Inorganic Chemistry ddc:540
Zdroj:	Jiao, Y, Sanz, S, Izarova, N V, Van Leusen, J, Sarwar, S, Dalgarno, S, Brechin, E K & Kögerler, P 2022, ' Hybrid lanthanide double-deckers based on calixarene and polyoxometalate units ', Dalton Transactions . https://doi.org/10.1039/D2DT00769J Dalton transactions 51(14), 5409-5413 (2022). doi:10.1039/D2DT00769J
ISSN:	1477-9234 1477-9226
Popis:	Complementarity of calixarene (H2L) and polyoxometalate ligands results in the first organic-inorganic [MIIIL{Mo5O13(OMe)4(NO)}]2–(M = Y, Gd and Dy) hybrid, directing the formation of a distorted square-antiprismatic MO8 ligand field, producing slow relaxation ofthe magnetisation for the Dy derivative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::56ee09b20d1617d7a34521365c859ae6 https://doi.org/10.1039/d2dt00769j Zobrazit plný text záznamu