Synthesis of benzo[a]carbazole derivatives from 3-ethylindoles by exploiting the dual character of benzoquinone as an oxidizing agent and dienophile
| Autor: | Lyu Lin, Ting Ta Chiang, Ching Fa Yao, Chun Wei Kuo, Chia Yu Huang, Ashok Konala, Veerababurao Kavala, Tang Hao Yang |
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| Rok vydání: | 2016 |
| Předmět: |
Diene
010405 organic chemistry Carbazole Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Benzoquinone Combinatorial chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Derivative (finance) chemistry Oxidizing agent Materials Chemistry Ceramics and Composites Organic chemistry |
| Zdroj: | Chemical communications (Cambridge, England). 52(50) |
| ISSN: | 1364-548X |
| Popis: | The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is generated in situ from the 3-ethylindole derivative with the help of benzoquinone, where it acts as an oxidizing agent. Later it serves as a dienophile and participates in a Diels–Alder reaction with the diene to afford benzo[a]carbazole derivatives. |
| Databáze: | OpenAIRE |
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