Efficient Synthesis of Substituted Polyarylphthalimides via Cycloaddition of Cyclopentadienones with 2-Bromomaleimide
| Autor: | Cathy Einhorn, Jacques Einhorn, Bernard Bessieres, Florian Berthiol, Remi Vanel |
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| Přispěvatelé: | Département de Chimie Moléculaire - Synthèse Et Réactivité en Chimie Organique (DCM - SeRCO), Département de Chimie Moléculaire (DCM), Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Decarbonylation Acenaphthene 010402 general chemistry 01 natural sciences Chemical synthesis Combinatorial chemistry Cycloaddition 0104 chemical sciences 3. Good health chemistry.chemical_compound chemistry Functional group Moiety [CHIM]Chemical Sciences Imide ComputingMilieux_MISCELLANEOUS Diels–Alder reaction |
| Zdroj: | SYNLETT SYNLETT, Georg Thieme Verlag, 2011, 2011 (09), pp.1293-1295. ⟨10.1055/S-0030-1260556⟩ |
| ISSN: | 0936-5214 1437-2096 |
| DOI: | 10.1055/S-0030-1260556⟩ |
| Popis: | Functionalized tetraarylphthalimides or diarylphthalimides fused with an acenaphthene moiety have been prepared in one step from 2-bromomaleimide and tetraarylcyclopentadienones (tetracyclones) or 7,9-diaryl-8H-cyclopentacenaphthylene-8-ones (acecyclones). The reaction, involving a cycloaddition―decarbonylation―dehydrobromination sequence, gives high isolated yields and is compatible with the presence of various functional groups. |
| Databáze: | OpenAIRE |
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