Efficient Route to 4a-Methyltetrahydrofluorenes: A Total Synthesis of (.+-.)-Dichroanal B via Intramolecular Heck Reaction
| Autor: | Manabu Node, Loic Planas, Hirofumi Takita, Tetsuya Kajimoto, Muneto Mogi |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Aldehydes
Fluorenes Intramolecular reaction Molecular Structure Diene Organic Chemistry Dichroanal B Total synthesis Stereoisomerism General Medicine Chemical synthesis Terpene chemistry.chemical_compound chemistry Cyclization Yield (chemistry) Heck reaction Intramolecular force Organic chemistry Diterpene Diterpenes |
| Zdroj: | ChemInform. 37 |
| ISSN: | 1522-2667 0931-7597 |
| DOI: | 10.1002/chin.200634188 |
| Popis: | An efficient new route based on intramolecular Heck cyclization of the diene 11 was developed to prepare the 4a-methyltetrahydrofluorene diterpenoids and utilized for the total synthesis of (+/-)-dichroanal B with significantly improved overall yield. |
| Databáze: | OpenAIRE |
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