Mechanism of biomass activation and ammonia modification for nitrogen-doped porous carbon materials
| Autor: | Kaixu Li, Hanping Chen, Wei Chen, Xin Tu, Sunwen Xia, Mingwei Xia, Yingquan Chen, Haiping Yang |
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| Rok vydání: | 2019 |
| Předmět: |
0106 biological sciences
Environmental Engineering Nitrogen chemistry.chemical_element Bioengineering 010501 environmental sciences Electric Capacitance 01 natural sciences Atmosphere Ammonia chemistry.chemical_compound 010608 biotechnology Biomass Porosity Waste Management and Disposal 0105 earth and related environmental sciences Supercapacitor Renewable Energy Sustainability and the Environment General Medicine Carbon Chemical engineering chemistry Reagent Charcoal Mesoporous material Pyrolysis |
| Zdroj: | BIORESOURCE TECHNOLOGY |
| ISSN: | 1873-2976 |
| Popis: | The effect of chemical activation and NH3 modification on activated carbons (ACs) was explored via two contrasting bamboo pyrolysis strategies involving either two steps (activation followed by nitrogen doping in NH3 atmosphere) or one step (activation in NH3 atmosphere) with several chemical activating reagents (KOH, K2CO3, and KOH + K2CO3). The ACs produced by the two-step method showed relatively smaller specific surface areas (∼90% micropores) and lower nitrogen contents. From the one-step method, the ACs had larger pore diameters with about 90% small mesopores (2–3.5 nm). Due to a promotion effect with the KOH + K2CO3 combination, the AC attained the greatest surface area (2417 m2 g−1) and highest nitrogen content (3.89 wt%), endowing the highest capacitance (175 F g−1). The balance between surface area and nitrogen content recommends KOH + K2CO3 activation via the one-step method as the best choice for achieving both greener production process and better pore structure. |
| Databáze: | OpenAIRE |
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