Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts
| Autor: | Ulysse Caniparoli, Imma Escofet, Antonio M. Echavarren |
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| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | ACS Catalysis |
| ISSN: | 2155-5435 |
| Popis: | Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalyst on the folding of the substrate in the chiral environment of the ligand involving attractive noncovalent interactions. |
| Databáze: | OpenAIRE |
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