Facile synthesis of enantioenriched phenol-sulfoxides and their aluminum complexes
| Autor: | Simon Duttwyler, Yani Tang, Yuji Sun, Jiyong Liu |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Sulfide 010405 organic chemistry Organic Chemistry Enantioselective synthesis chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences chemistry.chemical_compound chemistry Aluminium Phenol Organic chemistry Physical and Theoretical Chemistry Stoichiometry |
| Zdroj: | Organic & Biomolecular Chemistry. 14:5580-5585 |
| ISSN: | 1477-0539 1477-0520 |
| DOI: | 10.1039/c6ob00136j |
| Popis: | Chiral phenolic p-tolylsulfoxides and t-butylsulfoxides were prepared by several short synthetic routes starting from readily available starting materials. The key synthetic step was the reaction of lithiated arenes with menthyl sulfinates or enantioselective oxidation of a t-butyl sulfide. Well-defined neutral ligand-AlMe2 complexes were obtained by stoichiometric treatment with AlMe3. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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