Insertion of SO2 into a sulfide-bridged M-Ge bond: synthesis, characterization, and reactivity of the O-germyl-S-sulfoxylate

Autor:	Jeff W. Kampf, Zuzanna T. Cygan, Mark M. Banaszak Holl
Rok vydání:	2004
Předmět:	Inorganic Chemistry chemistry.chemical_classification Crystallography Sulfide Stereochemistry Chemistry Reactivity (chemistry) Crystal structure Physical and Theoretical Chemistry Characterization (materials science)
Zdroj:	Inorganic chemistry. 43(6)
ISSN:	0020-1669
Popis:	Addition of SO(2) to [formula: see text](1) results in the insertion of SO(2) into the Pd-Ge bond to give the O-germyl-S-sulfoxylate insertion isomer (Et3P)2Pd(mu-S)S(O)OGe[N(SiMe3)2]2 (2). Heating solutions of 2 results in the formation of (Et3P)Pd(SGe[N(SiMe3)2]2OSOGe[N(SiMe3)2]2S) (3) and a LnPd(0) fragment. X-ray crystal structures of 2 and 3 are reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::54a33df7a6c6b64eef8c2f1acc7f8eb5 https://pubmed.ncbi.nlm.nih.gov/15018529 Zobrazit plný text záznamu