Sorption of heavy metals by natural biopolymers
| Autor: | Alla P. Krasnopyorova, Galina D. Yuhno, Natalya V. Efimova, Anastasia A Scheglovskaya |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
General Chemical Engineering
Inorganic chemistry lcsh:QD450-801 Heavy metals Sorption lcsh:Physical and theoretical chemistry 02 engineering and technology Surfaces and Interfaces General Chemistry 010501 environmental sciences 021001 nanoscience & nanotechnology 01 natural sciences Ion Hydrolysis chemistry.chemical_compound Adsorption chemistry Ph range Lignin 0210 nano-technology 0105 earth and related environmental sciences |
| Zdroj: | Adsorption Science & Technology, Vol 35 (2017) |
| ISSN: | 2048-4038 0263-6174 |
| Popis: | The sorption properties of modified hydrolysis lignin towards Cu[Formula: see text], Zn[Formula: see text], Ni[Formula: see text], Co[Formula: see text] ions in the pH range from 2 to 8 at temperature of 298.15 K solution are studied. The analysis of kinetic curves of ions sorption on modified lignin at pH 7 shows that sorption equilibrium in heterogenic system ion–metal–sorbent is attained in 30–60 min. Obtained results indicate good equilibrium kinetic properties of sorbent. Supposed that reaction between sorbate and functional group of sorbent are the second-order reaction and they interact between each other in ratio 1:1. The character of the obtained electrokinetic curve suggests that the zeta potential of modified lignin strongly depends on the pH. The dependencies of cations metals sorption coefficients on the pH value of water phase are S-shaped. Maximal extraction of studied cations is observed at pH values of equilibrium solutions close to neutral ones. |
| Databáze: | OpenAIRE |
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