Heterogeneous Copper Catalyst for the Cycloaddition of Azides and Alkynes without Additives under Ambient Conditions
Autor: | In Soo Park, Youngkwon Kim, Jae Sung Lee, Jaiwook Park, Min Serk Kwon |
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Rok vydání: | 2008 |
Předmět: |
Azides
Molecular Structure Organic Chemistry One-pot synthesis Nanoparticle chemistry.chemical_element Biochemistry Copper Catalysis Cycloaddition Coupling reaction chemistry Cyclization Heterocyclic Compounds Alkynes Click chemistry Combinatorial Chemistry Techniques Organic chemistry Fiber Physical and Theoretical Chemistry Aluminum |
Zdroj: | Organic Letters. 10:497-500 |
ISSN: | 1523-7052 1523-7060 |
Popis: | A new copper catalyst was developed by immobilizing copper nanoparticles in aluminum oxyhydoxide fiber. The catalyst showed high catalytic activity for the (3+2) Huisgen cycloaddition of nonactivated alkynes as well as activated ones with various azides at room temperature. The catalyst was recycled five times without significant loss of activity. |
Databáze: | OpenAIRE |
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