Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
| Autor: | Kazuya Kanemoto, Suguru Yoshida, Yu Nakamura, Takamitsu Hosoya, Minori Suzuki |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
inorganic chemicals
Letter 010405 organic chemistry Aryl Organic Chemistry chemistry.chemical_element Sulfoxide 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Organosulfur compounds Palladium |
| Zdroj: | Organic Letters |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/acs.orglett.1c01292 |
| Popis: | An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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