Thermal, Morphological, and Biodegradability Properties of Bioplastic Fertilizer Composites Made of Oil Palm Biomass, Fertilizer, and Poly(hydroxybutyrate-co-valerate)
Autor: | Ahmad Saffian Harmaen, I. Nor Azowa, H. Mohd Ali, Abdan Khalina |
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Rok vydání: | 2016 |
Předmět: |
chemistry.chemical_classification
010407 polymers Materials science Article Subject Polymers and Plastics Scanning electron microscope 02 engineering and technology Polymer Biodegradation engineering.material lcsh:Chemical technology 021001 nanoscience & nanotechnology Valerate 01 natural sciences Bioplastic 0104 chemical sciences chemistry engineering lcsh:TP1-1185 Extrusion Fertilizer Fiber Composite material 0210 nano-technology |
Zdroj: | International Journal of Polymer Science, Vol 2016 (2016) |
ISSN: | 1687-9430 1687-9422 |
DOI: | 10.1155/2016/3230109 |
Popis: | Slow-release bioplastic fertilizer (BpF) composites were developed by processing oil palm empty fruit bunch (EFB), fertilizer, and poly(hydroxybutyrate-co-valerate) (PHBv) using extrusion techniques with controlled formulation and temperature. The temperature was kept at 150°C for 3 to 5 min during processing using twin-screw extruder. The PHBv lost weight gradually with the increasing temperature and its thermal degradation occurred initially at 263.4°C and reached the maximum at 300.7°C. Scanning electron microscope (SEM) images showed that the bonding of all composites created small gaps between matrices polymer and fiber because the hydrophilic characteristic of EFB fibers weakened the interfacial bonding. PHBv/EFB/NPKC2 showed faster biodegradation over PHBv/NPKC1 and PHBv/NPKC2, which was 99.35% compared to 68.66% and 90.28%, respectively. |
Databáze: | OpenAIRE |
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