[TcCl4(H2O)2] and [Cl3(H2O)2TcOTc(H2O)2Cl3]– two molecular intermediates of the hydrolysis of technetium(iv)

Autor:	Ulrich Abram, Adelheid Hagenbach, Eda Yegen
Rok vydání:	2005
Předmět:	Chemistry Metals and Alloys chemistry.chemical_element General Chemistry respiratory system Technetium Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Hydrolytic degradation Hydrolysis Tetrachloride Materials Chemistry Ceramics and Composites Organic chemistry
Zdroj:	Chemical Communications. :5575
ISSN:	1364-548X 1359-7345
DOI:	10.1039/b509686c
Popis:	Two molecular intermediates of the hydrolysis of technetium tetrachloride, cis-[TcCl4(H2O)2] and [Cl3(H2O)2TcOTc(H2O)2Cl3], were isolated and structurally characterised, suggesting that the hydrolytic degradation of technetium(IV) compounds occurs stepwise with the polymeric 'TcO2...nH2O' as a less defined final product.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::543403047262c127fd34167fc8f37463 https://doi.org/10.1039/b509686c Zobrazit plný text záznamu