A Protocol for Direct Stereospecific Amination of Primary, Secondary, and Tertiary Alkylboronic Esters

Autor:	James P. Morken, Emma K. Edelstein, Andrea C. Grote, Maximilian D. Palkowitz
Rok vydání:	2018
Předmět:	Primary (chemistry) 010405 organic chemistry Chemistry Organic Chemistry Enantioselective synthesis 010402 general chemistry 01 natural sciences Combinatorial chemistry Article 0104 chemical sciences chemistry.chemical_compound Stereospecificity Methoxyamine Amination
Zdroj:	Synlett. 29:1749-1752
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0037-1610172
Popis:	The direct, stereospecific amination of alkylboronic and borinic esters can be conducted by treatment of the organoboron compound with methoxyamine and potassium tert-butoxide. In addition to being stereospecific, this process also enables the direct amination of tertiary boronic esters in an efficient fashion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::53f9778ca7ea4e3a0388b6f0cdd230db https://doi.org/10.1055/s-0037-1610172 Zobrazit plný text záznamu