One-Pot Synthesis of Unsymmetric Diaryliodonium Salts from Iodine and Arenes

Autor:	Marcus Reitti, Erik Lindstedt, Berit Olofsson
Rok vydání:	2017
Předmět:	Organisk kemi 010405 organic chemistry Chemistry Organic Chemistry One-pot synthesis chemistry.chemical_element 010402 general chemistry Iodine 01 natural sciences 0104 chemical sciences Reagent Moiety Organic chemistry
Zdroj:	The Journal of Organic Chemistry. 82:11909-11914
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.7b01652
Popis:	The first synthesis of unsymmetric diaryliodonium salts directly from iodine and arenes is presented. The methodology provides diaryliodonium salts with the trimethoxyphenyl (TMP) moiety as dummy group. The protocol avoids the customary use of iodoarenes, which can be both expensive and toxic. Excess reagents are not required, and the reactions are performed under mild conditions. O-Arylations with these TMP salts were demonstrated to be highly chemoselective.
Databáze:	OpenAIRE
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