| Autor: |
Jim Simpson, C.J. McAdam, Anthony R. Manning, Donagh Courtney |
| Rok vydání: |
2011 |
| Předmět: |
|
| Zdroj: |
Acta Crystallographica Section E: Structure Reports |
| ISSN: |
1600-5368 |
| DOI: |
10.1107/s1600536811016928 |
| Popis: |
In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo-penta-dienyl and cyclo-butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo-butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo-penta-dienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C-H⋯π inter-actions which generate a three-dimensional network. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
