| Autor: |
Jian-Xin Wang, Ling-Ya Peng, Zheng-Fei Liu, Xin Zhu, Li-Ya Niu, Ganglong Cui, Qing-Zheng Yang |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
The Journal of Physical Chemistry Letters. 13:1985-1990 |
| ISSN: |
1948-7185 |
| DOI: |
10.1021/acs.jpclett.2c00168 |
| Popis: |
The modulation of the properties of emission from multiple emission states in a single-component organic luminescent material is highly desirable in data anticounterfeiting, information storage, and bioapplications. Here, a single-component luminescent organic crystal of difluoroboron diphenyl β-diketonate with controllable multiple emission colors is successfully reported. The temperature-dependent luminescence experiments supported by high-level theoretical calculations demonstrate that the ratio of the fluorescence between the monomer and excimer and the phosphorescence maxima of the excimer can be effectively regulated. In addition, the temperature-dependent fluorescence and afterglow dual-emission color changes provide a new strategy for the design of highly accurate double-checked temperature sensors. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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