Photocatalytic Decoloration of Cibacron Green RG12, on TiO2 Fixed on Mineral Supports by the PMTP Method
Autor: | M. Bouhelassa, N. Hadj Salah, B. David |
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Přispěvatelé: | LIPE (LIPE), Université Mentouri Constantine [Algérie] (UMC), Laboratoire de Chimie Moléculaire et Environnement (LCME), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]) |
Rok vydání: | 2011 |
Předmět: |
Anatase
Materials science deposed TiO2 02 engineering and technology Physics and Astronomy(all) 010501 environmental sciences 021001 nanoscience & nanotechnology 01 natural sciences law.invention Catalysis Reaction rate constant Chemical engineering law Phase (matter) Photocatalysis Calcination Reactivity (chemistry) [CHIM.OTHE]Chemical Sciences/Other 0210 nano-technology Photodegradation photocatalysis azo-dye 0105 earth and related environmental sciences |
Zdroj: | Physics Procedia Physics Procedia, Elsevier, 2011, 21, pp.115-121. ⟨10.1016/j.phpro.2011.10.017⟩ |
ISSN: | 1875-3892 |
DOI: | 10.1016/j.phpro.2011.10.017 |
Popis: | http://www.sciencedirect.com/science/article/pii/S1875389211006365; International audience; The aim of this study was to realize catalytic depositions of commercial titane dioxide on classic glass plates by the PMTPmethod, Previed Made Titanium Powder, and to characterize these deposits by MEB and DRX. As confirmed by SEM, three successive layers of photocatalyst are obtained on the glass plates in a quite homogeneous phase as well as it is confirmed that the anatase accounts for 75% after the calcination treatment by the PMTPmethod. The photocatalytic reactivity is evidenced with the determination of the rate constants of degradation of the dye cibacrongreenRG12, used as target, on the fixedTiO2 bed (0.010 min-1) compared to the direct photolysis in homogenous aqueous phase 0.001 min-1. Optimization of the process was explored by studying the dependence of the liquid flow rate and the absorption of photon by the photocatalyst on the kinetic rate constants of the dye photodegradation. |
Databáze: | OpenAIRE |
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