Controlled Synthesis of Hierarchical Pd Nanodendrites and Their Electrocatalytic Properties
| Autor: | Beibei Zeng, Yanxi Zhao, Hanfan Liu, Mei Li, Huan Wang, Tao Huang |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Nanostructure Atmospheric pressure Polyvinylpyrrolidone Formic acid Reducing agent Biomedical Engineering Bioengineering 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Oleylamide 0104 chemical sciences chemistry.chemical_compound chemistry Chemical engineering medicine General Materials Science 0210 nano-technology Stabilizer (chemistry) medicine.drug |
| Zdroj: | Journal of Nanoscience and Nanotechnology. 18:730-734 |
| ISSN: | 1533-4880 |
| DOI: | 10.1166/jnn.2018.13924 |
| Popis: | Well-defined hierarchical Pd nanodendrites with (111) surface were successfully synthesized with Pd(acac)2 as a precursor, polyvinylpyrrolidone (PVP) as a stabilizer, CO as a reducing agent in the presence of appropriate amounts of NaAc and oleylamide (OAm) at 100 °C for 3 h under atmospheric pressure. OAm played an important role in controlling the growth of the hierarchical dendritic nanostructures of the final products. The formation of the hierarchical Pd dendrites was ascribed to the OAm-confined growth from the tips along 〈111〉 axis directions. This kind of hierarchical Pd nanodendrites exhibited an enhanced electrocatalytic activity for the electro-oxidation of formic acid compared with Pd black. |
| Databáze: | OpenAIRE |
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