Non-scrambling of hydrogen in NH4+(H2O)3 clusters
| Autor: | Bertil Dynefors, Kristian Støchkel, S. Brøndsted Nielsen, A. E. K. Sundén, Klavs Hansen |
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| Rok vydání: | 2019 |
| Předmět: |
Heavy water
Hydrogen Chemistry General Chemical Engineering Analytical chemistry chemistry.chemical_element Protonation 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Ammonia chemistry.chemical_compound Deuterium Metastability Mass spectrum Molecule 0210 nano-technology |
| Zdroj: | Hansen, K, Sundén, A E K, Støchkel, K, Nielsen, S B & Dynefors, B 2019, ' Non-scrambling of hydrogen in NH 4 + (H 2 O) 3 clusters ', RSC Advances, vol. 9, no. 12, pp. 6620-6626 . https://doi.org/10.1039/c8ra10515d |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c8ra10515d |
| Popis: | We have measured the metastable decay of protonated, ammonia-doped, deuterated water clusters produced in an electrospray source, dn-NH4+(H2O)3, n = 0-6. The mass spectra show a very strong odd-even effect, consistent with a low degree of scrambling of the hydrogen bound to water and to the ammonia. The relative evaporation rate constant for light water was almost twice the one for heavy water, with the rate for mixed protium-deuterium water molecule intermediate between these two values. |
| Databáze: | OpenAIRE |
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