Different weak interactions in the crystals of three isomeric (E)-N-methyl-N′-(nitrobenzylidene)-2-(thiophen-2-yl)acetohydrazides
| Autor: | William T. A. Harrison, James L. Wardell, Laura N. F. Cardoso, Marcus V. N. de Souza, Thais C. M. Noguiera, Shaun T. Lancaster, Carlos R. Kaiser |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
crystal structure
Stereochemistry carbohydrazide methylation Stacking Thio General Chemistry Crystal structure Carbohydrazide 010402 general chemistry 010403 inorganic & nuclear chemistry Condensed Matter Physics Ring (chemistry) 01 natural sciences Research Communications weak hydrogen bonds 0104 chemical sciences lcsh:Chemistry chemistry.chemical_compound lcsh:QD1-999 chemistry Nitro General Materials Science methylation Benzene |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 12, Pp 1677-1682 (2016) Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| Popis: | Three isomeric methylated 2-(thiophen-2-yl)acetohydrazides show little consistency in the pattern of weak (C—H⋯O, C—H⋯π and π–π) interactions in their crystal structures. The crystal structures of three isomeric (E)-N-methyl-N′-(nitrobenzylidene)-2-(thiophen-2-yl)acetohydrazides (formula C14H13N3O3S) are described, with the nitro group in ortho, meta and para positions in the benzene ring. In each crystal structure, molecules are linked by various weak interactions (C—H⋯O and C—H⋯π bonds, and π–π stacking), leading to three-dimensional networks in each case, but with little similarity between them. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|