Rh(III)-Catalyzed Enone Carbonyl/Ketone-Directed Aerobic C–H Olefination of Aromatics with Unactivated Olefins

Autor:	Chikkabagilu Nagaraju Shambhavi, Masilamani Jeganmohan
Rok vydání:	2022
Předmět:	Chalcones Molecular Structure Organic Chemistry Acetophenones Alkenes Ketones Deuterium Norbornanes Catalysis
Zdroj:	The Journal of Organic Chemistry. 87:13236-13258
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.2c01730
Popis:	A Rh(III)-catalyzed weak enone carbonyl/ketone-assisted aerobic oxidative C-H olefination of aromatics with unactivated alkenes has been developed. This protocol involves cross-dehydrogenative Heck-type olefination reaction of various substituted biologically relevant chalcones and aromatic ketones such as acetophenones and chromones with various functionalized unactivated olefins in moderate to good yields. Further
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::531e8ae682a1f8ff0324b9b6b18cdb62 https://doi.org/10.1021/acs.joc.2c01730 Zobrazit plný text záznamu