Hollow Porous N and Co Dual-Doped Silicon@Carbon Nanocube Derived by ZnCo-Bimetallic Metal–Organic Framework toward Advanced Lithium-Ion Battery Anodes

Autor: Hongjung Kim, Jinhyuk Baek, Dong-Kyu Son, Michael Ruby Raj, Gibaek Lee
Rok vydání: 2022
Předmět:
Zdroj: ACS Applied Materials & Interfaces. 14:45458-45475
ISSN: 1944-8252
1944-8244
DOI: 10.1021/acsami.2c13607
Popis: Silicon (Si) has been recognized as a promising alternative to graphite anode materials for advanced lithium-ion batteries (LIBs) owing to its superior theoretical capacity and low discharge voltage. However, Si-based anodes undergo structural pulverization during cycling due to the large volume expansion (ca. 300-400%) and continuous formation of an unstable solid electrolyte interphase (SEI), resulting in fast capacity fading. To address this challenge, a series of different amounts of silicon nanoparticles (Si NPs)-encapsulated hollow porous N-doped/Co-incorporated carbon nanocubes (denoted as p-CoNC@Si
Databáze: OpenAIRE