Biomimetic Iodofunctionalization of Aromatic and Heteroaromatic Compounds Catalyzed by Selenium Tetrachloride
| Autor: | Givago P. Perecim, Beatriz C. O. Rocha, Cristiano Raminelli |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
aqueous reaction
Chemistry Materials Science (miscellaneous) Organic Chemistry Halogenation chemistry.chemical_element iodofunctionalization Iodine Catalysis Biomaterials lcsh:Chemistry chemistry.chemical_compound lcsh:QD1-999 Aqueous reaction selenium catalysis Biomimetic synthesis iodination Organic chemistry biomimetic synthesis Selenium tetrachloride |
| Zdroj: | SynOpen, Vol 03, Iss 04, Pp 142-147 (2019) |
| ISSN: | 2509-9396 |
| DOI: | 10.1055/s-0039-1690337 |
| Popis: | A biomimetic iodofunctionalization of aromatic and heteroaromatic compounds has been developed using NaI as a source of iodine and 30% H2O2 as a mild oxidant, as well as SeCl4 as a commercially available catalyst in water without a co-solvent. The method affords iodinated compounds in isolated yields of 37 to 99%. The catalytic system has potential for the bromination of aromatic substrates. |
| Databáze: | OpenAIRE |
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