Density, viscosity and intermolecular interaction of polyethylene glycol 300 + N, N-Dimethylformamide binary mixture
| Autor: | Jianbin Zhang, Yujie Pang, Long Zhao, Shuai Zhang, Zhaojun Wu, Xiaoqing Yue, Bin Li |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010304 chemical physics
Atmospheric pressure technology industry and agriculture Analytical chemistry Binary number 02 engineering and technology Polyethylene glycol Condensed Matter Physics 01 natural sciences Electronic Optical and Magnetic Materials Viscosity chemistry.chemical_compound 020401 chemical engineering chemistry Intermolecular interaction 0103 physical sciences PEG ratio Materials Chemistry N dimethylformamide 0204 chemical engineering Physical and Theoretical Chemistry |
| DOI: | 10.6084/m9.figshare.10184510 |
| Popis: | The density (ρ) and kinematic viscosity (v) data of polyethylene glycol 300 (PEG) + N, N-Dimethylformamide (DMF) binary mixture were determined under atmospheric pressure and six temperatures of T = (293.15–318.15) K. From these experimental results, the thermodynamic parameters like excess molar volume (VmE), apparent molar volume (Vφ,1 and Vφ,2) and partial molar volume (V1‾ and V2‾), viscosity deviation (Δη) and excess Gibbs activation free energy (ΔG*E) were systemically counted, in which the standard deviation between the experimental and calculated data was estimated by fitting the Redlich-Kister formula. The intermolecular interaction of DMF with PEG was analysed by FTIR and UV-vis spectral technologies. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|