Pd-catalyzed oxidative C–H alkenylation for synthesizing arylvinyltriazole nucleosides

Autor:	Fanqi Qu, Yuting Fan, Yi Xia, Ling Peng, Jingjie Tang, Mei Cong, Gilles Quéléver
Rok vydání:	2015
Předmět:	Chemistry Organic Chemistry Nucleosides Chemistry Techniques Synthetic Oxidative phosphorylation Alkenes Triazoles Biochemistry Catalysis chemistry.chemical_compound Heck reaction Organic chemistry Organic synthesis Physical and Theoretical Chemistry Oxidation-Reduction Nucleoside Palladium
Zdroj:	Organic & Biomolecular Chemistry. 13:110-114
ISSN:	1477-0539 1477-0520
Popis:	Various arylvinyltriazole nucleoside analogues were synthesized using Pd-catalyzed oxidative Heck reaction. This method affords the corresponding and otherwise difficult to achieve arylvinyltriazole nucleosides with good yields and large functional group compatibility. These results further advocate the potential and practicality of this oxidative C-H alkenylation method for generating structurally challenging chemical entities in organic synthesis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::52b0cff82368cd64278afe1f8e4f611c https://doi.org/10.1039/c4ob01836b Zobrazit plný text záznamu