Cationic rhodium(I)/segphos-catalyzed cycloisomerization of 1,6- and 1,7-diynes in the presence of 1,2-cyclohexanedione

Autor:	Ken Tanaka, Yousuke Otake, Masao Hirano
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Cycloisomerization SEGPHOS chemistry Organic Chemistry Cationic polymerization chemistry.chemical_element Physical and Theoretical Chemistry Biochemistry Medicinal chemistry Catalysis Rhodium
Zdroj:	Organic letters. 9(20)
ISSN:	1523-7060
Popis:	We have developed the first catalytic cycloisomerization of 1,6- and 1,7-diynes leading to trienes and vinylpyrroles by using a cationic rhodium(I)/Segphos complex (2.5−10 mol %) and 1,2-cyclohexanedione (100 mol %). 1,2-Cyclohexanedione may effectively occupy vacant coordination sites and thus promote the present cycloisomerization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5285b7f72734ab76ab6c74f9f09a912e https://pubmed.ncbi.nlm.nih.gov/17727289 Zobrazit plný text záznamu