Synthesis of Vinylic Sulfones in Aqueous Media

Autor:	Teck-Peng Loh, Manikantha Maraswami, Jeffrey Goh
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Aqueous medium 010405 organic chemistry Chemistry Organic Chemistry Functional group Organic chemistry Physical and Theoretical Chemistry 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences
Zdroj:	Organic Letters. 23:1060-1065
ISSN:	1523-7052 1523-7060
Popis:	A green method for the sulfination of allenic carbonyl compounds to access a wide variety of vinylic sulfones is developed. This reaction works in aqueous media under very mild conditions. This reaction is atom economic. A wide variety of vinylic sulfones could be obtained in moderate to excellent yields with wide functional group tolerance. The efficiency of this method is demonstrated in some reactions where the desired products can be isolated by filtration.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::51fbf83aa194e4b786026a2ef8a224d4 https://doi.org/10.1021/acs.orglett.0c04257 Zobrazit plný text záznamu