Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality
| Autor: | Steven D. Bull, Diane E. J. E. Robinson, Luke E. Turner, Philip Axe, William L. Mitchell, Carly J. Gilfillan, Matthew G. Davidson, Matthew D. Jones |
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| Rok vydání: | 2007 |
| Předmět: |
Models
Molecular Titanium Magnetic Resonance Spectroscopy Molecular Structure Ligand Organic Chemistry chemistry.chemical_element Stereoisomerism Crystallography X-Ray Ligands Biochemistry Sensitivity and Specificity Stereocenter chemistry.chemical_compound Enantiopure drug chemistry Alkoxide Polymer chemistry Organometallic Compounds Organic chemistry Amine gas treating Physical and Theoretical Chemistry Titanium isopropoxide Chirality (chemistry) |
| Zdroj: | Organic letters. 9(2) |
| ISSN: | 1523-7060 |
| Popis: | An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text]. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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