A helical coordination polymer of zinc(II), 4-hydroxybenzohydrazide and sulfate ions
| Autor: | Piotr Drożdżewski, Halina Zasłona, Maciej Barys |
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| Rok vydání: | 2012 |
| Předmět: |
Ions
Molecular Structure Chemistry Hydrogen bond Coordination polymer Ligand Stereochemistry Polymers Sulfates chemistry.chemical_element Hydrogen Bonding General Medicine Zinc Crystal structure Crystallography X-Ray General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound Crystallography Hydrazines Octahedral molecular geometry Helix Molecule |
| Zdroj: | Acta crystallographica. Section C, Crystal structure communications. 69(Pt 3) |
| ISSN: | 1600-5759 |
| Popis: | In the structure of the novel zinc complexcatena-poly[[diaqua(4-hydroxybenzohydrazide)zinc(II)]-μ-sulfato], [Zn(SO4)(C7H8N2O2)(H2O)2]n, the complex cations are linked by sulfate counter-ions into helical polymeric chains extending along thebaxis. Each helix is stabilized by six intrachain hydrogen bonds involving stronger O—H...O (1.83–2.06 Å) and weaker N—H...O (2.20–2.49 Å) interactions. The ZnIIatom displays a distorted octahedral geometry formed by the 4-hydroxybenzohydrazide ligand, two water molecules and two SO42−ions, which is very similar to the metal-atom environment in a previously reported CoIIcomplex [Zasłona, Drożdżewski & Kubiak (2010).J. Mol. Struct.982, 1–8], especially the Zn—O and Zn—N bond lengths of 2.0453 (12)–2.1602 (9) and 2.1118 (12) Å, respectively. |
| Databáze: | OpenAIRE |
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