Carbonylbiscaprolactam: A Versatile Reagent for Organic Synthesis and Isocyanate-Free Urethane Chemistry
| Autor: | Ton Loontjens, Boudewijn J. R. Scholtens, Rolf Mülhaupt, Steffen Maier |
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| Přispěvatelé: | Zernike Institute for Advanced Materials |
| Rok vydání: | 2003 |
| Předmět: |
Chemistry
carbamates General Chemistry Isocyanate Catalysis chemistry.chemical_compound polyurethane Reagent ComputingMethodologies_DOCUMENTANDTEXTPROCESSING synthetic methods Organic chemistry Organic synthesis coupling agents Selectivity GeneralLiterature_REFERENCE(e.g. dictionaries encyclopedias glossaries) Polyurethane |
| Zdroj: | Angewandte Chemie International Edition, 42, 5094-5097. WILEY-V C H VERLAG GMBH |
| ISSN: | 1521-3773 1433-7851 |
| DOI: | 10.1002/anie.200351867 |
| Popis: | Herewepresentthefirstcomprehensivestudiesonthereactionsof1withnucleophilessuchasaminesandalcohols.Special attention was paid to the influence of the reactionconditions—forexample,choiceofcatalyst,temperature,andstoichiometry of the reactants—on the selectivity and con-trollability of the reactions of 1. Controlling the numerousreactionpossibilitiesof1promisesmanifoldnewopportuni-ties.The chemistry of 1 is quite different from reactions ofphosgene,diisocyanates,and1,1’-carbonyldiimidazole(CDI).While CDI |
| Databáze: | OpenAIRE |
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