Nitrate-induced photooxidation of trace organic chemicals in water

Autor:	Richard G. Zepp, Heinz. Bader, Juerg. Hoigne
Rok vydání:	1987
Předmět:	Nitrobenzene chemistry.chemical_compound Nitrate chemistry Inorganic chemistry Environmental Chemistry Halide Quantum yield Hydroxyl radical General Chemistry Butyl chloride Anisole Chemical reaction
Zdroj:	Environmental Science & Technology. 21:443-450
ISSN:	1520-5851 0013-936X
DOI:	10.1021/es00159a004
Popis:	The oxidation kinetics of butyl chloride, nitrobenzene, anisole, and methylmercury in the presence of hydroxyl radical (OH) scavengers were used to determine the rate and quantum efficiency for production of OH from irradiated nitrate ions in water. The experiments were conducted under steady-state irradiations with monochromatic radiation (313 nm) and with sunlight. The mean quantum efficiency for OH production at 313 nm rises from 0.013 +/- 0.002 at 20 /sup 0/C to 0.017 +/- 0.003 at 30 /sup 0/C in the pH range 6.2-8.2. Results of this study are used to estimate nitrate-induced photooxidation rates of trace organic chemicals under a variety of environmental conditions. 27 references, 6 figures, 2 tables.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::51558674f7888842eef347c7963febe0 https://doi.org/10.1021/es00159a004 Zobrazit plný text záznamu