Synthesis of 10-Aza-9-oxakalkitoxin by N-O Bond Formation
| Autor: | Kapil Upadhyaya, David Crich |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Org Lett |
| Popis: | We describe a formal synthesis of 10-aza-9-oxakalkitoxin, the hydroxalog of the cytotoxic marine natural product kalkitoxin, that features Mukaiyama Markovnikov silyl peroxidation of a terminal alkene and N-O bond formation as the central enabling steps. |
| Databáze: | OpenAIRE |
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