A folded [2 × 2] metallo-supramolecular grid from a bis-tridentate (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligand

Autor:	Manuel Ruether, Bjørn la Cour Poulsen, Dawn E. Barry, Joseph P. Byrne, Thorfinnur Gunnlaugsson, Chris S. Hawes, John E. O'Brien
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry Ligand Supramolecular chemistry Solid-state 010402 general chemistry Grid 01 natural sciences Solution phase 0104 chemical sciences Inorganic Chemistry Crystallography Product (mathematics) Chelation QD
Zdroj:	Dalton transactions (Cambridge, England : 2003). 46(19)
ISSN:	1477-9234 1477-9226
Popis:	A flexible ditopic ligand 1 containing two N,N,O-tridentate (1,2,3-triazol-4-yl)-picolinamide chelating pockets is reported and the formation of multimetallic architectures is explored in the solid and the solution phase. The self-assembled ZnII complex [Zn4(1)4](ClO4)8 exhibited a folded [2 × 2] square grid supramolecular architecture that selectively assembled in MeCN solution as shown using various spectroscopic techniques. The closely related FeII complex shows equivalent behaviour in the solid state, while a discrete dinuclear species [Cu2(NO3)41]·5MeCN was the sole product observed in the solid state from the reaction between 1 and CuII under similar conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5107cb12674cd84567f9a8b556fe0e10 https://pubmed.ncbi.nlm.nih.gov/28470292 Zobrazit plný text záznamu