A facile photosynthesis of trans-dioxoruthenium(VI) porphyrins
| Autor: | Yan Huang, Eric Vanover, Rui Zhang |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Steric effects
Photodissociation Metals and Alloys General Chemistry Photosynthesis Photochemistry Porphyrin Medicinal chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Bond cleavage Visible spectrum |
| Zdroj: | Chemical communications (Cambridge, England). 46(21) |
| ISSN: | 1364-548X |
| Popis: | Photolysis of porphyrin-ruthenium(IV) dichlorate complexes with visible light results in homolytic cleavage of the O–Cl bond in the chlorates to form trans-dioxoruthenium(VI) species bearing either sterically encumbered or unencumbered porphyrin ligands. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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