Formation of organorhodium complexes via C–H bond activation of 1,3-di(phenylazo)benzene

Autor:	Michael G. B. Drew, Paramita Majumder, Haregewine Tadesse, Suparna Baksi, Sarmistha Halder, Alexander J. Blake, Samaresh Bhattacharya
Rok vydání:	2011
Předmět:	Inorganic Chemistry chemistry.chemical_compound C h bond Chemistry Stereochemistry Ligand Benzene
Zdroj:	Dalton Transactions. 40:5423
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c1dt10247h
Popis:	Reaction of a potential NCN-pincer ligand, viz. 1,3-di(phenylazo)benzene (L), with [Rh(PPh(3))(3)Cl] affords, via a C-H bond activation, an interesting dinuclear Rh(II) complex (1), and with RhCl(3)·3H(2)O affords a mononuclear Rh(III) complex (2) containing a catalytically useful Rh-OH(2) fragment.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::50ca699b32b8516caec113ff88b737d0 https://doi.org/10.1039/c1dt10247h Zobrazit plný text záznamu