Modulation of Photodeprotection by the Sunscreen Protocol

Autor:	Or Eivgi, Efrat Levin, N. Gabriel Lemcoff
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Light source Chemistry Modulation Organic Chemistry Molecule Alcohol Physical and Theoretical Chemistry Chromophore Molar absorptivity Photochemistry Protecting group Biochemistry
Zdroj:	Organic Letters. 17:740-743
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.5b00019
Popis:	A protocol for the selective photoremoval of alcohol protecting groups modulated by the presence of auxiliary light absorbing molecules is presented. Thus, by this method, a single light source was used to selectively remove a specific protecting group in the presence of another chromophore with a lower molar absorption coefficient. The use of a molecular sunscreen, either internal or external, was found to be crucial to achieve high selectivities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::50af9eb8b4d1dc77db431067b1a9fed6 https://doi.org/10.1021/acs.orglett.5b00019 Zobrazit plný text záznamu