In tandem or alone: a remarkably selective transfer hydrogenation of alkenes catalyzed by ruthenium olefin metathesis catalysts

Autor:	Karol Grela, Grzegorz Zielinski, Cezary Samojłowicz, Tomasz Wdowik
Rok vydání:	2015
Předmět:	Organic Chemistry chemistry.chemical_element Noyori asymmetric hydrogenation Metathesis Transfer hydrogenation Biochemistry Ruthenium Catalysis chemistry Salt metathesis reaction Ring-opening metathesis polymerisation Organic chemistry Physical and Theoretical Chemistry Acyclic diene metathesis
Zdroj:	Organicbiomolecular chemistry. 13(9)
ISSN:	1477-0539
Popis:	A system for transfer hydrogenation of alkenes, composed of a ruthenium metathesis catalyst and HCOOH, is presented. This operationally simple system can be formed directly after a metathesis reaction to effect hydrogenation of the metathesis product in a single-pot. These hydrogenation conditions are applicable to a wide range of alkenes and offer remarkable selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::501f0ff6b457d47554f8307f0254db1a https://pubmed.ncbi.nlm.nih.gov/25586518 Zobrazit plný text záznamu