Why is Mn charge ordered and AFM coupled in YBaMn2O5?

Autor:	Pavel Karen
Rok vydání:	2022
Předmět:	Inorganic Chemistry Materials Chemistry Ceramics and Composites Physical and Theoretical Chemistry Condensed Matter Physics Electronic Optical and Magnetic Materials
ISSN:	0022-4596
Popis:	Synthesis conditions to obtain single-phase YBaMn2O5 are reported and its crystal structure refined from neutron powder diffraction data collected between 25 and 600 ​°C in the paramagnetic state. The structure parameters are used to reason why the phase maintains ordered ionic charges of Mn instead of mixing them at an elevated temperature, why this Mn2+ and Mn3+ ordering is of the checkerboard type in all three dimensions, and why these ions would couple antiferromagnetic upon cooling.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4fe28602a3521d530e3da3d92146d63c http://hdl.handle.net/10852/95552 Zobrazit plný text záznamu Full Text from ScienceDirect