2-O-Benzylation in D-Gluconamide Derivative Under Basic Conditions with Complete Retention of Stereo-Integrity: Convenient Access to 2-O-benzyl-3,4:5,6- di-O-isopropylidene-D-glucitol and other Differently Protected D-glucitol Derivatives
Autor: | Indrapal Singh Aidhen, B. N. Manjunath, Kommidi Harikrishna, Babu Varghese |
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Rok vydání: | 2009 |
Předmět: | |
Zdroj: | Journal of Carbohydrate Chemistry. 28:264-277 |
ISSN: | 1532-2327 0732-8303 |
DOI: | 10.1080/07328300902979503 |
Popis: | A new and convenient synthesis of 2-O-benzyl-3, 4: 5, 6-di-O- isopropylidene-D-glucitol has been accomplished and has been generalized with the syntheses of differently protected D-glucitols at C-2 position. In the course of our new route to the differently protected D-glucitols at C-2 position, a new D-gluco configured building block, 1-morpholino-(3, 4: 5, 6-di-O-isopropylidene)-D-gluconamide has been achieved. |
Databáze: | OpenAIRE |
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