The crystal structure of bis[ethylenediamine]copper(II)fluorophosphatehydrate, Cu(en)2(PF6)2 · H2O
| Autor: | K. G. Keramidas, P. J. Rentzeperis |
|---|---|
| Rok vydání: | 1991 |
| Předmět: |
chemistry.chemical_classification
Chemistry Inorganic chemistry chemistry.chemical_element Ethylenediamine Crystal structure Condensed Matter Physics Copper Inorganic Chemistry chemistry.chemical_compound Crystallography Hexafluorophosphate X-ray crystallography Molecule General Materials Science Hydrate Inorganic compound |
| Zdroj: | Zeitschrift für Kristallographie - Crystalline Materials. 194:273-280 |
| ISSN: | 2196-7105 2194-4946 |
| DOI: | 10.1524/zkri.1991.194.14.273 |
| Popis: | The title compound is orthorhombic, with space group B2mb and Z = 4. The cell dimensions are a = 8.66036(1) Å, b = 14.51489(5) Å and c = 13.25635(6) Å. A total of 1626 independent reflections were measured with a SYNTEX P21 automatic diffractometer using MoKα radiation. The structure was refined by a full-matrix least-squares procedure to a conventional R = 0.055 for the 1556 unique reflections. The co-ordination around the central copper atom is octahedral with the copper atom 0.78(4) Å above the equatorial plane of the four nitrogen atoms of the ligand molecule. The Cu – N equatorial plane bond lengths are 1.975 and 2.031 Å. The remaining positions of the co-ordination octahedron are occupied by a fluorine atom of one of the fluorophosphate groups and an oxygen of a water molecule. The Cu – F and Cu – O bond lengths are 2.7371 Å and 2.3968 Å respectively. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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