Theoretical enhancement of solar cell efficiency by the application of an ideal ‘down-shifting’ thin film

Autor: S.O. Martin, A. B. Wedding, C.P. Thomas
Přispěvatelé: Thomas, Christopher Paul, Wedding, Anthony Bruce, Martin, Stewart Oliver
Rok vydání: 2012
Předmět:
Zdroj: Solar Energy Materials and Solar Cells. 98:455-464
ISSN: 0927-0248
DOI: 10.1016/j.solmat.2011.11.027
Popis: Poor ultraviolet (UV) quantum conversion efficiency contributes to a reduction in the efficiency of silicon based photovoltaic cells. In the UV, the main loss mechanism is through surface recombination of photo-generated carriers due to the shallow absorption depth of high energy photons. One method for greater utilisation of the UV region is by down-shifting UV photons to lower energies where the quantum efficiency of silicon is higher. This work determines the potential enhancement in efficiency that can be obtained by a luminescent down-shifting layer applied to silicon based solar cells. The efficiency is determined through detailed balance arguments. The maximum calculated efficiency enhancement due to an ideal down shifting process is 0.6% absolute using the AM1.5G standard spectra. Applying a similar analysis to a multicrystalline silicon solar cell results in an efficiency enhancement due to the down-shifting process of 0.17% absolute. Refereed/Peer-reviewed
Databáze: OpenAIRE