Transition-Metal π-Ligation of a Tetrahalodiborane

Autor:	J. Oscar C. Jiménez-Halla, Rian D. Dewhurst, Holger Braunschweig, Jonas H. Muessig, Eduard Matito
Rok vydání:	2017
Předmět:	Crystallography Transition metal 010405 organic chemistry Chemistry Stereochemistry chemistry.chemical_element Halide General Chemistry 010402 general chemistry Platinum 01 natural sciences Catalysis 0104 chemical sciences
Zdroj:	Angewandte Chemie International Edition. 57:412-416
ISSN:	1433-7851
Popis:	The reaction of tetraiododiborane (B2I4) with trans- [Pt(BI2)I(PCy3)2] led to isolation of the diplatinum(II) complex [{(Cy3P)(I2B)Pt}2(μ2:h3:h3-B2I4)], supported by the bridging diboranyl dianion ligand [B2I4]2-. The complex is the first transition metal complex of a diboranyl dianion, as well as the first example of intact coordination of a B2X4 (X = halide) unit of any type to a metal center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4f70a475f85f8819fbefecb427e57c0c https://doi.org/10.1002/anie.201709515 Zobrazit plný text záznamu Plný text